<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bento, M. F.</style></author><author><style face="normal" font="default" size="100%">Pereira, H.</style></author><author><style face="normal" font="default" size="100%">Cunha, M. Á</style></author><author><style face="normal" font="default" size="100%">Moutinho, A. M. C.</style></author><author><style face="normal" font="default" size="100%">van den Berg, K. J.</style></author><author><style face="normal" font="default" size="100%">Boon, J. J.</style></author><author><style face="normal" font="default" size="100%">van den Brink, O.</style></author><author><style face="normal" font="default" size="100%">Heeren, R. M. A.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Fragmentation of Suberin and Composition of Aliphatic Monomers Released by Methanolysis of Cork from Quercus suber L.,Analysed by GC-MS, SEC and MALDI-MS</style></title><secondary-title><style face="normal" font="default" size="100%">Holzforschung</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Cork</style></keyword><keyword><style  face="normal" font="default" size="100%">MALDI-MS</style></keyword><keyword><style  face="normal" font="default" size="100%">Methanolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Quercus suber L.</style></keyword><keyword><style  face="normal" font="default" size="100%">SEC</style></keyword><keyword><style  face="normal" font="default" size="100%">Suberin fragmentation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2005///</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">55</style></volume><pages><style face="normal" font="default" size="100%">487 - 493</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Suberin from extractive-free cork from Quercus suber L. was depolymerised by methanolysis using different sodium methanolate (NaOMe) concentrations. 1% and 3% NaOMe completely removed suberin from cork (54%–56% of extractive-free cork), but for lower concentrations there was incomplete solubilisation; with 0.05% NaOMe, only approximately 80% of total suberin was removed. The monomeric composition of the extracts differed significantly: for the 0.05% NaOMe, only alkanoic acids and diacids were found; the yield of v-hydroxy acids increased with reactant concentration, as well as alkanols and ferulic acid. Results from light scattering, SEC and MALDI-MS showed that soluble oligomeric fragments containing suberinic acids were present in the methanolysis mixture. The molecular weight of these oligomeric fragments decreased with higher sodium methanolate concentrations.</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Filomena Bento, M.</style></author><author><style face="normal" font="default" size="100%">Aurea Cunha, M.</style></author><author><style face="normal" font="default" size="100%">Moutinho, A. M. C.</style></author><author><style face="normal" font="default" size="100%">Pereira, H.</style></author><author><style face="normal" font="default" size="100%">FORTES, M. A.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">A mass spectrometry study of thermal dissociation of cork</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Mass Spectrometry and Ion Processes</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Cork</style></keyword><keyword><style  face="normal" font="default" size="100%">electron-induced fragmentation</style></keyword><keyword><style  face="normal" font="default" size="100%">thermal dissociation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">1992</style></year><pub-dates><date><style  face="normal" font="default" size="100%">1992///</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://www.sciencedirect.com/science/article/pii/016811769280004K</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">112</style></volume><pages><style face="normal" font="default" size="100%">191 - 204</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Mass spectrometry has proved a convenient technique for the analysis of plant cell-wall material. In this work a comparative study is made of chemically treated cork and untreated cork, applying a method in which samples were continuously heated in vacuum. The outgassing products, upon electron-induced fragmentation, are analysed by a quadrupole mass spectrometer. Sequence of spectra at increasing temperatures were obtained for each sample, which allowed identification of the main groups of fragmentation. From such sequences of spectra one may derive intensity—temperature curves for each peak. Analysis of these curves for samples subjected to different treatments proved useful to identify the peaks, to assign the component which originates the species and even to derive activation energies.</style></abstract><issue><style face="normal" font="default" size="100%">2–3</style></issue></record></records></xml>